2,2′-{1,1′-[Butane-1,4-diyl­bis(oxy­nitrilo)]di­ethylidyne}di-1-naphthol

نویسندگان

  • Wen-Kui Dong
  • Jian-Chao Wu
  • Yin-Xia Sun
  • Jian Yao
  • Jun-Feng Tong
چکیده

The title compound, C(28)H(28)N(2)O(4), was synthesized by the reaction of 2-acetyl-1-naphthol with 1,4-bis-(amino-oxy)butane in ethanol. The molecule, which lies about an inversion centre, adopts a linear structure, in which the oxime groups and naphthalene ring systems assume an anti conformation. The intra-molecular inter-planar distance between parallel naphthalene rings is 1.054 (3) Å. Intra-molecular O-H⋯N hydrogen bonds are formed between the oxime nitro-gen and hydr-oxy groups.

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منابع مشابه

Terephthalic acid–2,2′-dimethyl-1,1′-(butane-1,4-di­yl)dibenzimidazole (2/3)

In the crystal structure of the title compound, 2C(8)H(6)O(4)·3C(20)H(22)N(4), there are three independent 2,2'-dimethyl-1,1'-(butane-1,4-di-yl)dibenzimidazole mol-ecules, each of which lies on an inversion centre. The terephthalic acid mol-ecules are linked to adjacent 2,2'-dimethyl-1,1'-(butane-1,4-di-yl)dibenzimidazole mol-ecules via O-H⋯N hydrogen bonds.

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In the title coordination polymer, [Zn(C(8)H(4)O(5))(C(14)H(22)N(4))](n), the Zn(II) cation is coordinated by an O(2)N(2) donor set in a distorted tetra-hedral geometry. The Zn(II) ions are linked by μ(2)-OH-bdc (OH-H(2)bdc = 5-hy-droxy-isophthalic acid) and bbie ligands [bbie = 2,2'-diethyl-1,1'-(butane-1,4-di-yl)diimidazole], forming a two-dimensional layer parallel to the ab plane. The layer...

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catena-Poly[[dichloridozinc(II)]-μ-[1,1′-(butane-1,4-di­yl)diimidazole-κ2 N 3:N 3′]]

The title one-dimensional coordination polymer, [ZnCl(2)(C(10)H(14)N(4))](n), was synthesized by hydro-thermal methods from ZnCl(2) and 1,1'-(butane-1,4-di-yl)diimidazole. The Zn atom is coordinated by two chloride ions and two N atoms from two symmetry-independent organic ligands and shows a distorted tetra-hedral coordination geometry. The 1,1'-(butane-1,4-di-yl)diimidazole ligands are locate...

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عنوان ژورنال:

دوره 65  شماره 

صفحات  -

تاریخ انتشار 2009